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Technická 5
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Copyright: UCT Prague 2015
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All publications of our authors (since 2015): here
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k Phonebook of the Department | |||
Professors: |
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Prof. Radek Cibulka e +420 22044 4182 d A 278c |
Head of Department | www | ResearcherID |
Prof. Pavel Lhoták e +420 22044 5055 d A 249 |
www | ||
Prof. Jaroslav Kvíčala e +420 22044 4240 d A 278d |
www | ||
Prof. Jiří Svoboda e +420 22044 3688 d A 278e |
www | ||
Associate Professors: |
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Assoc. Prof. Jan Budka e +420 22044 4284 d A 251 |
DOC web editor | www | |
Assoc. Prof. Jana Hodačová e +420 22044 4173 d A 270 |
www | ||
Assoc. Prof. Michal Kohout e +420 22044 5012 d A 258 |
www | ||
Assoc. Prof. Igor Linhart e +420 22044 4165 d A 266 |
www | ||
Assoc. Prof. Tomáš Tobrman e +420 22044 4245 d A 271 |
RIT | www | |
Assistant Professors: |
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Dr. Michal Himl e +420 22044 4165 d A 266 |
www | ||
Dr. Roman Holakovský e +420 22044 4279 d A 255 |
www | ||
Dr. Petr Kovaříček e +420 22044 2040 d B3 207 |
www | ||
Dr. Václav Kozmík e +420 22044 4118 d A 308 |
www | ||
Dr. Martin Krupička e +420 220 444 173 |
www | ||
Dr. Ondřej Kundrát e +420 22044 4280 d A 253 |
www | ResearcherID | |
Dr. Petra Ménová e +420 22044 3686 d A 268 |
www | ||
Dr. Pavla Perlíková e +420 22044 2039 d B3 206 |
www | ||
Dr. Markéta Rybáčková e +420 22044 4242 d A 259 |
Secretary of Department |
www | |
Dr. Eva Svobodová e +420 22044 4249 d A 260 |
www | ||
Technicians: |
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Květa Bártová e +420 22044 3686 d A 268 |
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Ivana Bocková, MSc. e +420 22044 4280 d A 250 |
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Michaela Kadlecová
e +420 22044 4276 d A 262 b Michaela.Kadlecova@vscht.cz |
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Martina Kovandová e +420 22044 4279 d A 255 |
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Vladimír Kuneš e +420 22044 4277 d A L06 |
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Jana Netušilová e +420 22044 4164 d A 278a |
Administrative Support of Department | ||
Markéta Slabochová, MSc. e +420 22044 4059 d A 308 |
Economist of Department | ||
Helena Štenglová e +420 22044 4278 d A 257 |
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Ing. David Tetour e +420 22044 4173 d A270 |
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Marta Tokárová e +420 220 444 245 d A 271 |
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Essential Information for Current Students
Bachelor Students
Master Students
PhD Students
Lectures delivered by members of the Department
- Toxicology and ecology
- Organic chemistry I, II and III
- Structural analysis
- Reactivity of organic compounds
- Molecular design
- Organic synthesis I and II
- Quantum organic chemistry
- Farmacochemistry
- Organic stereochemistry
- Organometallic chemistry
- Organic chemistry of selected elements
DATA
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Current group members
Students: |
PhD students: |
Assoc. Prof.: |
Jiří Lapčík | Peter Polák | Tomáš Tobrman |
Marek Čubiňák | Hana Váňová | |
Eliška Fikejzová |
Technician: |
|
Filip Gracias | Marta Tokárová | |
Roman Valeš | ||
Václav Vraštil | ||
Petr Oeser | ||
Jakub Koudelka |
Our alumni:
PhD students: | Master students: | Bachelor students: |
|
|
|
Marek Čubiňák
Department of Organic Chemistry
UCT Prague
Technická 5
166 28 Praha 6
tel: +420 220 444 245
fax: +420 220 444 288
marek.cubinak@vscht.cz
PhD thesis:
Stereoselective synthesis of tetrasubstituted alkenes.
Publications:
Diastereoselective Cyclopropanation through Michael Addition‐Initiated Ring Closure between α,α‐Dibromoketones and α,β‐Unsaturated Fischer Carbene Complexes.
Eur. J. Org. Chem. 2020, 429-436. DOI: 10.1002/ejoc.201901503
Tobrman, T.; Čubiňák, M.; Dvořák, D.: Stereoselective synthesis of trisubstituted alkenyl Fischer aminocarbenes through self-mediated α-haloketone olefination.
J. Organomet. Chem. 2019, 902, 120971. DOI 10.1016/j.jorganchem.2019.120971
Čubiňák, M.; Edlová, T.; Polák, P.; Tobrman, T.: Indolylboronic Acids: Preparation and Applications.
Molecules 2019, 24, 3523 DOI: 10.3390/molecules24193523
Tobrman, T.; Polák, P.; Čubiňák, M.; Dvořáková, H.; Dvořák, D.: Dichotomy within 1,4-addition of organolithium and Grignard reagents to α,β-unsaturated Fischer alkoxycarbenes: A new synthesis of Fischer carbenes.
Tetrahedron 2019, 75, 2175-2181. DOI: 10.1016/j.tet.2019.02.038
Čubiňák, M.; Eigner, V.; Tobrman, T.: Bench‐Stable Sulfoxide‐Based Boronates: Preparation and Application in a Tandem Suzuki Reaction.
Adv. Synth. Catal. 2018, 360, 4604-4614. DOI:10.1002/adsc.201801000
The page has not been synthesized yet..
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- Vanova, H.; Tobrman, T.; Hoskovcova, I.; Dvorak, D.:
Modular synthesis of Fischer biscarbene complexes of chromium
Organometallics 2016, 35, 2999-3006 DOI:10.1021/acs.organomet.6b00527 - Kotek, V.; Polák, P.; Dvořáková, H.; Tobrman, T.:
Aluminium Chloride Promoted Cross-Coupling of Trisubstituted Enol Phosphates with Organozinc Reagents En Route to the Stereoselective Synthesis of Tamoxifen and Its Analogues
Eur. J. Org. Chem. 2016, 5037-5044 DOI:10.1002/ejoc.201600959 - Polák, P.; Váňová, H.; Dvořák, D.; Tobrman, T.:
Recent Progress in Transition Metal-Catalyzed Stereoselective Synthesis of Acyclic All-Carbon Tetrasubstituted Alkenes
Tetrahedron Lett. 2016, 57, 3684-3693 DOI:10.1016/j.tetlet.2016.07.030 - Kotek, V.; Polák, P.; Tobrman, T.:
Efficient and Simple Preparation of Functionalized 1,1-Dibromoenol Phosphates
Monatshefte fuer Chemie 2016, 147, 405-412 DOI:10.1007/s00706-015-1613-6
2015
- Kotek V., Dvořáková H., Tobrman T.: Modular and highly stereoselective approach to all-carbon tetrasubstituted alkenes. Org. Lett., 2015, 17, 608-611
- Křováček M., Dvořák D.: Synthesis of potentially biologically active 6-(1,3-butadiynyl)purines. J. Heterocyclic Chem., 2015, 52, 40-47
- Tobrman T., Jurásková I., Dvořák D.: Negishi cross-coupling reaction as a simple and efficient route to functionalized amino and alkoxy carbene complexes of chromium, molybdenum, and tungsten. Organometallics, 2014, 33, 6593-6603
- Kvapilová H., Eigner V., Hoskovcová I., Tobrman T., Čejka J., Záliš S.: Structural flexibility of 2-hetaryl chromium aminocarbene complexes: Experimental and theoretical evidence. Inorg. Chim. Acta, 2014, 421, 439-445
- Vrzal L., Flídrová K., Tobrman T, Dvořáková H., Lhoták, P.: Use of residual dipolar couplings in conformational analysis of meta-disubstituted calix[4]arenes. Chem. Commun., 2014, 50, 7590-7592
- Tobrman T, Jurásková I., Váňová H., Dvořák D: Lithiation of chromium and tungsten aminocarbene complexes: An easy approach to functionalized aminocarbene complexes. Organometallics, 2014, 33, 2990-2996
- Tobrman T., Dvořák D.: Regioselective and facile synthesis of 7,9-dialkyl-8-oxopurines from 7,9-dialkyl-7,8-dihydropurines: Total synthesis of Heteromines I and J. Synthesis, 2014, 46, 660-668
- Maryška M., Chudíková N., Kotek V., Dvořák D., Tobrman T.: Regioselective and efficient synthesis of N7-substituted adenines, guanines, and 6-mercaptopurines. Monatsh Chem, 2013, 144, 501-507
- Koukal P., Dvořáková H., Dvořák D., Tobrman T.: Palladium-Catalyzed Claisen Rearrangement of Allyloxypurines. Chemical Papers, 2013, 67, 3-8
- Metelková R., Tobrman T., Kvapilová H., Hoskovcová I., Ludvík J.: Synthesis, characterization and electrochemical investigation of hetaryl chromium(0) aminocarbene complexes. Electrochimica Acta, 2012, 82, 470-477
- Kotek V., Tobrman T., Dvořák D.: Highly Efficient and Broad-Scope Protocol for the Preparation of 7-Substituted 6-halopurines via N9-Boc-Protected 7,8-dihydropurines. Synthesis 2012, 44, 610-618
- Hoskovcová I., Zvěřinová R., Roháčová J., Dvořák D., Tobrman T., Záliš S., Ludvík J: Fischer aminocarbene complexes of chromium and iron: Anomalous electrochemical reduction of p-carbonyl substituted derivatives. Electrochimica Acta 2011, 56, 6853-6859
- Tobrmanová M., Tobrman T., Dvořák D.: Pd-Catalyzed Allylic Substitution of Purin-8-yl(allyl) Acetate: Route to (E)-Alkenylpurines. Collect. Czech. Chem. Commun. 2011, 76, 311-326
- Hoskovcova I., Dvorak D., Tobrman T., Zalis S., Ludvik J.: Key structural features in electrochemistry of Cr(0) and Fe(0) aminocarbene complexes Monograph Series of the International Conferences on Coordination and Bioinorganic Chemistry held periodically at Smolenice in Slovakia 2011, 10, 155-169
- Negishi E.-i., Tobrman T., Rao H., Xu S., Lee Ch.-T.: Highly (98 %) Selective Alkene Synthesis of Wide Applicability via Fluride-Promoted Pd-Catalyzed Cross-Coupling of Alkenylboranes. Isr. J. Chem. 2010, 50, 696-701
- Kotek V., Chudíková N., Tobrman T., Dvořák D.: Selective Synthesis of 7-substituted Purines via 7,8-dihydropurines. Org. Lett. 2010, 12, 5724-5727
- Pařík P., Kulhánek J., Ludwig M., Wagner R., Rotrekl I., Drahoňovský D., Meca L., Šmídková M., Tobrman T., Dvořák D.: Acidity of Benzoic Acids Bearing the (CO)5Cr=CN(CH3)2 Group. Organometallics 2010, 29, 4135-4138
- Hoskovcová I., Roháčová J., Dvořák D., Tobrman T., Záliš S., Zvěřinová R., Ludvík J.: Synthesis and electrochemical study of iron, chromium and tungsten aminocarbenes: Role of ligand structure and central metal nature. Electrochimica Acta, 2010, 55, 8341-8351
- Klečka M., Křováček M., Tobrman T., Dvořák D.: Synthesis of (E)-6-Alkenylpurines via Pd-Catalyzed Stannation/Protodestannation Tandem Process of Alkynylpurines. Collect. Czech. Chem. Commun. 2010, 75, 313-332
- Wang C., Xu Z., Tobrman T., Negishi E.-i.: Arylethyne Bromoboration-Negishi Coupling Route to E- or Z-Aryl-Substituted Trisubstituted Alkenes of >98% Isomeric Purity. New Horizon in the Highly Selective Synthesis of Trisubstituted Alkenes. Adv. Synth Catal., 2010, 352, 627-631
- Wang C., Tobrman T., Xu Z., Negishi E.-i.: Highly Regio- and Stereoselective Synthesis of (Z)-Trisubstituted Alkenes via Propyne Bromoboration and Tandem Pd-Catalyzed Cross-Coupling. Org. Lett. 2009, 11, 4092-4095
- Keder R., Dvořáková H., Dvořák D.: New Approach to the Synthesis of N-7-Arylguanines and N-7-Aryladenines. Eur. J. Org. Chem. 2009, 1522-1531
- Tobrman T., Dvořák D.: Heck reactions of 6- and 2-halopurines. Eur. J. Org. Chem. 2008, 2923–2928
- Krouželka J., Linhart I., Tobrman T.: Synthesis of 3-(2-hydroxy-1-phenylethyl)- and 3-(2-hydroxy-2-phenylehtyl)adenine, DNA adducts derived from styrene. J. Heterocyclic Chem. 2008, 45, 789–795
- Tobrman T., Štepnička P., Císařová I., Dvořák D.: Preparation and crystal structures of purine 2,2’-, 6,6’-, and 8,8’-dimers. Eur. J. Org. Chem. 2008, 2167–2174
- Tobrman T., Dvořák D.: Reductive Dimerization of 2- and 6-Iodopurines: Side reaction in Pd-Catalyzed Cross Coupling of Iodopurines. Collect. Czech Chem. Comm. 2007, 72, 1365-1374
- Tobrman T., Dvořák D.: Selective magnesiation of chloro-iodopurines: An efficient approach to new purine derivatives. Org. Lett. 2006, 8, 1291-1294
- Tobrman T., Meca L., Dvořáková H., Černý J., Dvořák D.: Study of the Origin of the Hindered Rotation of an Aryl Ring in the Chromium Aminocarbene Complexes Bearing Aromatic Ring Atteched to the Carbene Carbon Atom. Organometalics 2006, 25, 5540-5548
- Klečka M., Tobrman T., Dvořák D.: Cu(I)-catalyzed coupling of (9-benzylpurin-6-yl)magnesium chloride with allyl halides: an approach to 6-allylpurine derivatives. Collect. Czech Chem. Comm. 2006, 71, 1221-1228
- Hoskovcová I., Roháčová J., Meca L., et al.: Electrochemistry of chromium(0)-aminocarbene complexes: The use of intramolecular interaction LFER for characterization of the oxidation and reduction centre of the complex. Electrochimica Acta 2005, 50(25-26), 4911-4915
- Drahoňovský D., Štěpnička P., Dvořák D.: P-chiral 2-{1 '-[butyl(phenyl)phosphanyl]ferrocen-1-yl} -4-isopropyl-4,5-dihydrooxazoles: A second chirality center in catalytic system. Collect. Czech Chem. Comm. 2005, 70, 361-369
- Meca L., Dvořák D., Ludvík J., et al.: Synthesis, structures, and electrochemistry of group 6 aminocarbenes with a P-chelating 1'-(Diphenylphosphino)ferrocenyl substituent Organometallics 2004, 23, 2541-2551
- Tobrman T., Dvořák D.: 'Reductive Heck reaction' of 6-halopurines Tetrahedron Lett. 2004, 45, 273-276
- Tobrman T., Dvořák D.: 6-magnesiated purines: Preparation and reaction with aldehydes. Org. Lett. 2003, 5, 4289-4291
- Hocek M., Dvořák D., Havelková M.: Covalent analogues of nucleobase-pairs. Nucleoside Nucleotides & Nucleic Acids 2003, 22, 775-777
- Meca L., Císařová I., Dvořák D.: Thermolysis of iron N-allylaminocarbene complexes: Formation of eta(3)-1-azaallylirontricarbonyl complexes. Synthetic and theoretical study. Organometallics 2003, 22, 3703-3709
- Drahoňovský D., Borgo V., Dvořák D.: Fischer chromium carbene complexes as nucleophiles in palladium-catalyzed allylic substitution reactions. Tetrahedron Lett. 2002, 43, 7867-7869
- Havelková M., Dvořák D., Hocek M.: Covalent analogues of DNA base-pairs and triplets. Part 3: Synthesis of 1 ,4-and 1,3-bis(purin-6-yl)benzenes and 1-(1,3-dimethyluracil-5-yl)-3 or 4-(purin-9-yl)benzenes. Tetrahedron 2002, 58, 7431-7435
- Havránek M., Dvořák D.: 3,3-disubstituted allyl alcohols from palladium-catalyzed coupling of hydroaluminated propargyl alcohols with aryl iodides. J. Org. Chem. 2002, 67, 2125-2130
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- Havránek M., Dvořák D.: 3-(tributylstannyl)allyl alcohols: Useful building blocks for solid-phase synthesis of skipped dienes and trienes. Collect. Czech. Chem. Commun. 2000, 65, 434-454
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