Wait a second...
Nepřihlášený uživatel
You are here: VŠCHT PrahaFCHTÚOCH  → Research groups → Kvíčala → Research
iduzel: 38642
idvazba: 40913
šablona: stranka
čas: 15.7.2024 19:18:10
verze: 5420
branch: trunk
Obnovit | RAW
iduzel: 38642
idvazba: 40913
---Nová url--- (newurl_...)
domena: 'uoch.vscht.cz'
jazyk: 'en'
url: '/research-groups/kvicala-en/research'
iduzel: 38642
path: 8548/6214/6521/6526/7837/22301/38642
CMS: Odkaz na newurlCMS
branch: trunk
Obnovit | RAW

Current topics studied in our group:

  • Chiral NHC ligands and fluorination reagents
  • Ring opening metathesis of strained fluorocycloalkenes
  • Computational studies of reaction mechanisms
  • Chiral fluorous recyclable ruthenium and palladium catalysts

We have developed polyfluoroalkylated Hoveyda-Grubbs second-generation precatalyst analogues and PEPPSI catalyst analogues, that can be recycled using medium fluorous separation methods. This approach utilizes hydrofluoroethers such as HFE 7100 or HFE 7500, which are environmentally acceptable in comparison to perfluorinated solvents.

  • Ring-closing metathesis of prochiral oxaendiynes

Prochiral oxaendiynes undergo chemoselective ring-closing metathesis affording 2H-pyran derivatives, which can be further transformed into tricyclic compounds via chemo- and stereoselective Diels-Alder reaction.

Updated: 1.3.2021 15:14, Author: Ondřej Kundrát

UCT Prague
Technická 5
166 28 Prague 6 – Dejvice
IČO: 60461373 / VAT: CZ60461373

Czech Post certified digital mail code: sp4j9ch

Copyright: UCT Prague 2015
Information provided by the Department of Organic Chemistry. Technical support by the Computing Centre.
switch to desktop version