In the last years, we have been focusing on inherently chiral derivatives which can be obtained via relatively simple reactions in the meta-position of a (thia)caliarene skeleton (see publications); some examples of last results: |
Intramolecularly Bridged Calix[4]arenes with Pronounced Complexation Ability toward Neutral CompoundsSlavik, P.; Eigner, V.; Lhotak, P.
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Shaping of Calix[4]arenes via Double Bridging of the Upper Rim Slavik, P.; Eigner, V.; Lhotak, P.
Abstract: Direct double meta-mercuration can be used for subsequent bridging of a calix[4]arene skeleton via the installation of ketone moieties. This unprecedented substitution pattern in calixarene chemistry possesses a heavily distorted and rigid cavity capable of interactions with selected molecular guests as documented by binding of a CH2Cl2 molecule held in place by an intricate net of 10 specific (halogen bonding and hydrogen bonding) interactions from two neighbouring calixarene molecules |
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Updated: 10.1.2017 22:40, Author: Ondřej Kundrát